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聚合物電池化學(xué)

2023-05-23



鋰離子電池包括液體鋰離子電池(LIB)和鋰聚合物電池(PLIB)。其中,液態(tài)鋰離子電池是指嵌入式負(fù)極二次電池。使用鋰化合物L(fēng)ICOO2、LiniO2或Limn2O4,負(fù)極使用鋰-碳間化合物L(fēng)IXC6。典型的蓄電池系統(tǒng)是:


(-)C|Lipf6 EC+12c|LICOO2(+)


陽(yáng)性反應(yīng):LICOO2=li1-xCoo2+xli++xe-


陰性反應(yīng):6C+XLI++XE-=lixc6


電池總響應(yīng):LICOO2+6C=li1-xCoo2+lixc6


鋰聚合物電池的原理與液態(tài)鋰相同,主要區(qū)別在于電解質(zhì)與液態(tài)鋰不同。電池的主要結(jié)構(gòu)包括三個(gè)元素:正極、負(fù)極和電解質(zhì)。所謂的鋰聚合物電池


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