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方形鋰電池低溫哪個好?

2022-11-12

方形鋰電池

方形低溫鋰電池主要有兩種形式,一種是硬殼鋁殼方形鋰電池,另一種是鋁塑膜軟包方形鋰電池。這兩種方形低溫鋰電池有什么區(qū)別,哪種低溫電池更好?讓我們看看。

1、鋁殼方形鋰電池

(1) 鋁殼方形鋰電池采用卷繞式生產(chǎn)工藝,因此在相同容量下,體積和重量均高于軟殼方形鋰電池。

(2) 鋁殼方形鋰電池采用的電解液為液態(tài),在低溫環(huán)境下易結(jié)冰,內(nèi)阻大大增加,影響電池的放電能力,甚至產(chǎn)生析鋰,允許電池在低溫環(huán)境下運行。

(3) 鋁殼將有被電解液腐蝕的危險,導(dǎo)致液體泄漏和報廢。

(4) 但是,鋁殼方形鋰電池在實現(xiàn)增加容量和并聯(lián)連接方面具有相對較好的優(yōu)勢。

(5) 液體電解質(zhì)在電解反應(yīng)后容易產(chǎn)生氣體,從而導(dǎo)致電池膨脹和爆裂。因此,鋁殼電池配有安全閥,防止爆炸事故。

(6) 鋁殼鋰電池外殼變形能力差,容易造成損壞。

2、鋁塑膜軟包方形鋰電池

鋁塑膜軟包方形鋰電池有幾種電解質(zhì),一是液體電解質(zhì),一是膠體電解質(zhì),另一種是固體電解質(zhì)。不同的電解質(zhì),低溫方形鋰電池具有不同的耐低溫性。

根據(jù)目前這三種電解質(zhì)的應(yīng)用實踐,固體電解質(zhì)的方形鋰電池的低溫性能是好的,因為固體電解質(zhì)不會因溫度而凍結(jié)物質(zhì),影響正常放電。由于固體電解質(zhì)本身的化學(xué)缺陷,就電子電導(dǎo)率而言,它是三種電解質(zhì)中低的。固態(tài)鋰電池在超低溫環(huán)境下具有高的容量效率,但無法實現(xiàn)倍率放電。-30 ℃ 以上的放電可以實現(xiàn)低速率放電。

膠體低溫鋰電池在中低溫環(huán)境下放電容量理想,但比固態(tài)低溫鋰電池稍差,液態(tài)差。


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