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鋰電池陶瓷隔膜的優(yōu)缺點

2022-11-03

鋰電池

鋰電池陶瓷隔膜采用陶瓷顆粒包覆,即以PP、PE或多層復(fù)合隔膜為基體,表面包覆一層Al203、SiO2、Mg (OH)2或其他優(yōu)異的耐熱性無機(jī)陶瓷顆粒經(jīng)特殊工藝處理后與基材緊密結(jié)合,使有機(jī)物的柔韌性和無機(jī)物的熱穩(wěn)定性穩(wěn)定結(jié)合,提高隔膜的耐高溫性、耐熱收縮性和穿刺強(qiáng)度,進(jìn)而提高電池的安全性能。據(jù)了解,陶瓷復(fù)合層一方面可以解決PP、PE隔膜熱收縮導(dǎo)致的熱失控導(dǎo)致電池燃燒爆炸的安全問題; 另一方面,陶瓷復(fù)合隔膜與電解液、正負(fù)電極材料具有良好的浸潤性。吸收液體和保留液體的能力大大提高了鋰電池的使用壽命。此外,陶瓷涂層隔板還可以中和電解質(zhì)中的少量氫氟酸,以防止電池膨脹。

氧化鋁用鋰電池陶瓷隔膜的性能要求:

1,粒徑均勻,可以很好地粘合到膜片上,而不會阻塞膜片孔。

2,氧化鋁純度高,不能引入雜質(zhì),影響電池的內(nèi)部環(huán)境。

3,氧化鋁晶體結(jié)構(gòu)的要求,保證了氧化鋁與電解質(zhì)的相容性和潤濕性。

涂層高純度氧化鋸 (VK-L30G) 隔膜的優(yōu)點:

1、耐高溫:

氧化鋁涂層具有優(yōu)異的耐高溫性,可以保持180攝氏度以上的隔膜形態(tài)。

2、高安全性:

氧化鋁涂層可以中和電解液中的自由場,提高電池的耐酸性,提高安全性。

3、高速率性能:

納米氧化鋁可以在粘結(jié)電池中形成固溶體,提高倍率和循環(huán)性能。

4、良好的潤濕性:

納米氧化鋁粉末具有良好的液體吸收和保留能力。

5、獨特的自關(guān)機(jī)特性:

保持聚烯烴隔膜的閉孔特性,以避免熱失控引起的安全跡象。

6、低自放電率:

氧化鋁涂層增加了微孔的曲折程度,自放電比普通隔膜低。

7、長循環(huán)壽命:

減少了循環(huán)過程中的機(jī)械微短路,有效提高了循環(huán)壽命。


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